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  Qiao-Sheng Hu

Research Publications

60.“Macromolecular Effect: Synthesis of Monophosphine-Containing Polymers for Transition Metal Catalysis." Hu, Q.-S.; Lu, Y.; Tang, Z.-Y.; Yu, H.-B. J. Am. Chem. Soc. 2002, submitted.

59.Non-Traditional Step-Growth Polymerization: Transition Metal Coupling.” Hu, Q.-S. Invited review for publication in “Synthetic Methods for Step-Growth Polymers” Ed. Rogers, M.; Long, T. Wiley, 2002, in press.

58.“Optically Active Dendronized Polymers as a New Type of Macromolecular Chiral Catalysts for Asymmetric Catalysis.” Hu, Q.-S.; Sun, C.; Monaghan, C. E. Tetrahedron Lett. 2002, 43, 927.

57.“Synthesis of an Ephedrine-Bearing Optically Active Poly(phenyleneethynylene) for Asymmetric Catalysis.” Sun, C.; Hu, Q.-S. Polymer Preprints 2002, 43, 692.

56.“A Practical Enantioselective Fluorescent Sensor for Mandelic Acid.” Lin, J.; Hu, Q.-S.; Yan, X.-L.; Xu, M.-H.; Pu, L. J. Am. Chem. Soc. 2002, 124, 2088.

55."A Binaphthyl-Bithiophene Copolymer for Light-Emmitting Devices." Liu, Y.; Yu, G.; Jen, A. K.-Y.; Hu, Q.-S.; Pu, L. Macromol. Chem. Phys.. 2002, 203, 37.

54.“Synthesis of Optically Active Polymers Containing Chiral Units Attached to Rigid Backbones and their Application for Asymmetric Catalysis.” Hu, Q.-S.; Sun, C.; Monaghan, C. E. Tetrahedron Lett. 2001, 42, 7725.

53.“Synthesis and Study of Optically Active Polydendrimers.” Wyatt, S. R.; Hu, Q.-S.; Yan, X.-L.; Bare, W. D.; Pu, L. Macromolecules 2001, 34, 7983.

52.“Optically Active BINOL Core-Based Phenyleneethynylene Dendrimers for the Enantioselective Fluorescent Recognition of Amino Alcohols." Pugh, V. J.; Hu, Q.-S.; Zuo, X.; Lewis,F. D.; Pu, L. . J. Org. Chem. 2001, 66, 6136.

51.“Optically Active Dendrimers with a Binaphthyl Core and Phenylene Dendrons: Light Harvesting and Enantioselective Fluorescent Sensing." Gong, L. -Z.; Hu, Q. -S.; Pu, L. J. Org. Chem. 2001, 66, 2358.

50.“The First Optically Active BINOL-BINAP Copolymer Catalyst: Highly Stereoselective Tandem Asymmetric Reactions.” Yu, H.-B.; Hu, Q.-S.; Pu, L. J. Am. Chem. Soc. 2000, 122, 6500.

49.“Immobilization of Heterobimetallic Multifunctional Asymmetric Catalyst.” Arai, T.; Hu, Q.-S.; Zheng, X. F.; Pu, L.; Sasai, H. Org. Lett. 2000, 2, 4261.

48.“The First Dendrimer-Based Enantioselective Fluorescent Sensor for the Recognition of Chiral Amino Alcohols.” Pugh, V.; Hu, Q.-S.; Pu, L. Angew. Chem. 2000, 39, 3638.

47.“Synthesis of Chiral PolyBINAP for Asymmetric Catalysis.” Yu, H.-B.; Hu, Q.-S.; Pu, L. Tetrahedron Lett. 2000, 41, 1681.

46.“Synthesis of Rigid Chiral Polymers for Asymmetric Diels-Alder Reactions.” Hu, Q.-S.; Pu, L. Polymer Preprints. 2000, 41(1), 16.

45.“Structurally Rigid and Optically Active Dendrimers.” Hu, Q.-S.; Pugh, V.; Sabat, M.; Pu, L. J. Org. Chem. 1999, 64, 7528.

44.“From Highly Enantioselective Monomeric Catalysts to Highly Enantioselective Polymeric Catalysts:Application of Rigid and Sterically Regular Chiral Binaphthyl Polymers in the Asymmetric Synthesis to Chiral Secondary Alcohols.” Huang, W.-S.; Hu, Q. –S.; Huang, W.-S.; Pu, L. J. Org. Chem. 1999, 64, 7940.

43.“Asymmetric Epoxidation of a,b-Unsaturated Ketones Catalyzed by Chiral Polybinaphthyl Zinc Complexes: Greatly Enhanced Enantioselectivity by a Cooperation of the Catalytic Sites in a Polymer Chain.” Yu, H. –B.; Zheng, X. –F.; Lin, Z. –M.; Hu, Q. –S.; Huang, W.-S.; Pu, L. J. Org. Chem. 1999, 64, 8149.

42.“Efficient Light-Emitting Diodes Based on a Novel Binaphthalene-Containing Polymer.” Liu, Y.; Jen, A. K.-Y.; Hu, Q.-S.; Pu, L. Applied Physics Lett. 1999, 75, 3745.

41.“The First Chiral Polymer Catalyzed Highly Diastereo- and Enantioselective Cycloaddition Reaction of Nitrones with Alkenes.” Simonsen, K. B.; Jorgenson, K. A.; Hu, Q. –S.; Pu, L. Chem. Comm. 1999, 811.

40.“A Highly Enantioselective Hetero-Diels-Alder Reaction Catalyzed by Chiral Polybinaphthyl-Aluminum Complexes.” Johannsen, M.; Jorgenson, K. A.; Zheng, X. –F.; Hu, Q. –S.; Pu, L. J. Org. Chem. 1999, 64, 299.

39.“Chiral Polymers in Asymmetric Catalysis: an Optically Active Polybinaphathyl-Ti(IV) Catalyst for an Asymmetric Alkyl Addition to Aldehydes.” Yu, H. –B.; Zheng, X. –F.; Hu, Q. –S.; Pu, L. Polymer Preprints, 1999, 40(1), 546.

38.“A New Approach to Highly Enantioselective Polymeric Chiral Catalysts.” Hu, Q. –S.; Huang, W. –S.; Pu, L. J. Org. Chem. 1998, 63, 2798.

37.“Characterization of Novel Optically Active Conjugated Polyarylenes and Poly(aryleneethylene)s by a Combination of Laser Light Scattering and Gel Permeation Chromatography.” Kwan, C. M. S.; Hu, Q. –S.; Ma, L.; Pu, L. Wu, C. J. Polym. Sci. Part A: Polym. Physics 1998,36, 2615.

36.“A Highly General Catalyst for Enantioselective Reaction of Aldehydes with Diethylzinc.” Huang, W. –S.; Hu, Q. –S.; Pu, L. J. Org. Chem. 1998, 63, 1364.

35.“Synthesis of Binaphthyl-Oligothiophene Copolymers with Emmisions of Different Colors: Systematically Tuning the Photoluminescene of Conjugated Polymers”, Musick, K. Y.; Hu, Q. –S.; Pu, L. Macromolecules, 1998, 31, 2933.

34.“Synthesis of an Optically Active Minor-Groove Poly-Binaphthyl and Its Application in Asymmetric Catalysis.” Lin, Z. –M.; Hu, Q. –S.; Pu, L. Polymer Preprints, 1998, 39(1), 235.

33.“Functionalized Major-Groove and Minor-Groove Chiral Polybinaphthols: Application in the Asymmetric Reaction of Aldehydes with Diethylzinc.” Hu, Q. –S.; Huang, W. –S.; Vitharana, D.; Zheng, X. –F.; Pu, L. J. Am. Chem. Soc, 1997, 119, 12454.

32.“Development of Highly Enantioselective Polymeric Catalysts Using Rigid and Sterically Regular Chiral Polybinaphthols.” Huang, W. –S.; Hu, Q. –S.; Zheng, X. –F.; Anderson, J.; Pu, L. J. Am. Chem. Soc. 1997, 119, 4313.

31.“A New Class of Chiral Conjugated Polymers with a Propeller-Like Structure.” Ma, L.; Hu, Q. –S.; Vitharana, D.; Wu, C.; Kwan, C. S.; Pu, L. Macromolecules, 1997,30, 204.

30.“Femtosecond Studies of Exciton Dynamics in a Novel Main Chain Chiral Conjugated Poly(aryllenevinylene).” Zhang, J. Z.; Kreger, M. A.; Hu, Q. –S.; Vitharana, D.; Pu, L.; Brock, P. J.; Scott, J. C. J. Chem. Phys. 1997, 106, 3710.

29.“A Facile Synthesis of Per(poly)fluoroalkyl Substituted a-Amino Acid Derivatives.” Hu, Q. –S.; Hu, C. –M. Chin. J. Chem. 1997, 15, 286.

28.“Study on the Sulfinatodehalogenation of BrCF2CF2R.” Hu, Q. –S.; Hu, C. –M.; Huang, W.-Y. Chin. J. Chem. 1997, 15, 472.

27.“Reformastky Reaction of Ethyl 4,4-Difluoro-3-Ethoxy-4-Halo Crotonate: Synthesis of 4,4-Difluorobutenoate Derivatives and Lactenones.” Hu, Q. –S.; Hu, C. –M. J. Fluorine Chem. 1997, 83, 87.

26.“A Facile Synthesis of Per(poly)fluoroalkyl Substituted Electrophilic Cyclo-propane Derivatives.” Hu, Q. –S.; Hu, C. –M. J. Fluorine Chem. 1997, 83, 185.

25.“Addition of Per(poly)fluoroalkyl Iodides to Vinyl Cyclopropane Derivatives: Synthesis of Fluoroalkyl Substituted g, d-Unsaturated Carbonyl compounds.” Hu, Q. -S.; Hu, C. –M. Chin. Chem. Lett. 1997, 8, 565.

24.“BrCo(dmgh)2Py/zn Promoted Addition of BrCF2CF2CH=CHCH2X to Alkynes: Direct Synthesis of 4,4,5,5-Tetrafluoro-cyclopentene Derivatives.” Hu, Q. –S.; Hu, C. –M. Chin. Chem. Lett. 1997, 8, 661.

23.“Michael Addition of Nitroalkanes to CF3CCl2COCH=CHPh: A Facile Route to Fluorine-Containing g-Nitro Ketones.” Hu, Q. –S.; Hu, C. –M. Chin. Chem. Lett. 1997, 8, 665.

22.“Studies on the Sulfinatodehalogenation of BrCF2CFClR: Synthesis of Trifluorovinyl Compounds.” Hu, Q. –S.; Hu, C. –M. Chin. Chem. Lett. 1997, 8, 669.

21.“[3+2] Cycloaddition of Ethyl 3-Fluoroalkyl-3-Haloacrylate with CH2N2.” Hu, Q. –S.; Hu, C. –M. Chin. Chem. Lett. 1997, 8, 673.

20.“Poly(1,1’-bi-2-naphthyl)s: Synthesis, Characterization, and Application in Lewis Acid Catalysis.” Hu, Q. –S.; Vitharana, D.; Zheng, X. –F.; Wu, C.; Kwan, C. M. S.; Pu, L. J. Org. Chem. 1996, 61, 8370.

19.“The First Optically Active and Sterically Regular Poly(1,1’-bi-2-naphthol): Precursors to a New Generation of Polymeric Catalysts.” Hu, Q. –S.; Zheng, X. –F.; Pu, L. J. Org. Chem. 1996, 61, 5200.

18.“Conjugated Polymers with Main Chain Chirality. 1. Synthesis of an Optically Active Poly(Arylenevinylene).” Hu, Q. –S.; Vitharana, D.; Liu, G.; Jain, V.; Wagaman, M. W.; Zhang, L.; Lee, T.; Pu, L. Macromolecules, 1996, 29, 1082.

17.“Conjugated Polymers with Main Chain Chirality. 2. Synthesis of Optically Active Poly(Arylenes).” Hu, Q. –S.; Vitharana, D.; Liu, G.; Jam, V.; Pu, L. Macromolecules, 1996, 29, 5075.

16.“Conjugated Polymers with Main Chain Chirality. 3. Synthesis of Optically Active Poly(Aryleneethynylenes).” Ma, L.; Hu, Q. –S.; Musick, K.; Vitharana, D.; Wu, C.; Kwan, C. M. S.; Pu, L. Macromolecules, 1996, 29, 5083.

15.“Femtosecond Studies of Exciton Dynamics in a Novel Optically Active Conjugated Polymer.” Zhang, J. Z.; Kreger, M. A.; Goka, E. H.; Pu, L.; Hu, Q. –S.; Vitharana, D.; Rothberg, L. J. Springer Ser. Chem. Phys. 1996, 62, 284.

14.“Synthesis of a 1,1’-Binaphthyl Based Main Chain Chiral Conjugated Polymer.” Hu, Q. –S.; Vitharana, D.; Pu, L. in Electrical, Optical and Magnetic Properties of Organic Solid State Materials III, Jen, A. K. –Y.; Lee, C. Y.-C.; Dalton, L. R.; Rubner, M. F.; Wnek, G.E.; Chiang, L.Y. Ed., MRS: Pittsburgh; 1996, p.621.

13.“An Optically Active Polybinaphthyl. Nickel(0) Mediated Polymerization of 6,6’-Dibromo-2,2’-dihexyloxy-1,l’-binaphthyl.” Vitharana, D.; Hu, Q. –S.; Pu, L. Polymer Preprints, 1996, 37, 855.

12.“Chiral Conjugated Propeller Polymers.” Ma, L.; Hu, Q. –S.; Vitharana, D.; Pu, L. Polymer Preprints, 1996, 37, 462.

11.“Synthesis of an Optically Active Poly-(aryleneethynylene) Containing Extended Conjugation in the Repeat Unit.” Ma, L.; Hu, Q. –S.; Pu, L. Tetrahedron: Asymmetry, 1996, 7, 3103.

10.“The First Sterically Regular Chiral Conjugated Crown Ether Polymer.” Cheng, H.; Ma, L.; Hu, Q. –S.; Zheng, X. –F.; Anderson, J.; Pu, L. Tetrahedron: Asymmetry, 1996, 7, 3083.

9.“Synthesis of 3-Hydroxy-5-Per(poly)fluoroalkyl Pyrazoles.” Hu, Q. –S.; Guan, H. –P.; Hu, C. –M. J. Fluorine Chem. 1996, 75, 51.

8.“NiCl2/Al Promoted Addition of Per(poly)fluoroalkyl Iodides to Per(poly)fluoroalkyl Substituted Ethenes.” Hu, Q. –S.; Hu, C. –M. J. Fluorine Chem. 1996, 76, 117.

7.“Direct Synthesis of 3-Fluoroalkyl-2,6-Diethoxycarbonyl Phenols.” Guan, H. –P.; Hu, Q. –S.; Hu, C. –M. Chin. J. Chem. 1996, 14, 87.

6.“Synthesis of 2-Substituted 6-Fluoro-Alkylpyrimidin-4(3H)-ones and –Pyrimidines.” Guan, H. –P.; Hu, Q. –S.; Hu, C. –M. Synthesis, 1996, 997.

5.“An Efficient and Practical Direct Resolution of Racemic 1,l’-Bi-2-naphthol to Both of Its Pure Enantiomers.” Hu, Q. –S.; Vitharana, D.; Pu, L. Tetrahedron: Asymmetry, 1995, 6, 2123.

4.“Synthesis of Functionalized Trifluorovinyl Compounds.” Hu, C. –M.; Hu, Q. –S.; Qiu, Y. –L.; Chen, J. J. Fluorine Chem. 1994, 66, 171.

3.“A Modified Synthesis of Optically Pure (4S, 8R) and (4S, 8S)-p-methene-8,9-diols.” Xu, X.-X.; Hu, Q. –S. Acta Chimica Sinica (in Chinese), 1994, 52, 89.

2.“Synthesis and Configuration of the Degradation Product of Yingzhaosu B.” Xu, X.-X.; Hu, Q. –S. Chin. Chem. Lett. 1993, 4, 885.

1.“Synthesis of the Diastereoisomeric Yingzhaosu D.” Xu, X.-X.; Hu, Q. –S. Chin. J. Chem. 1992, 10, 285